期刊
INORGANIC CHEMISTRY
卷 54, 期 17, 页码 8769-8777出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b01397
关键词
-
资金
- Japan Society for the Promotion of Science [24107005]
- Grants-in-Aid for Scientific Research [24107005] Funding Source: KAKEN
A series of highly luminescent trinuclear and tetranuclear ring-shaped Re(I) complexes wherein the Re units are linked with rigid bidentate phosphine ligands, namely, bis(diphenylphosphino)-p-phenylene, -trans-vinylene, and -ethynylene, were synthesized and fully characterized. Their strong emissive properties and the long lifetimes of their triplet metal-to-ligand charge transfer excited states originate primarily from enhanced, rigidity-induced interligand interactions between the 2,2'-bipyridine (bpy) ligand and the phenyl groups of the phosphine ligands. In addition, another type of interligand interaction was also observed between the bpy ligand and the phosphine-bridging group; this interaction also strongly affected the photophysical and redox properties of the Re-rings.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据