期刊
INORGANIC CHEMISTRY
卷 54, 期 5, 页码 2088-2090出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic502884z
关键词
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资金
- National Natural Science Foundation of China [21272110, 21273101, 21171173]
- Foundation of the Program for Backbone Teachers in Universities of Henan Province [2013GGJS151, 2012GGJS158]
- Tackle Key Problem of Science and Technology Project of Henan Province, China [142102310483]
- Science Foundation of Henan Education Department [14A150049]
- Innovation Scientists and Technicians Troop Construction Projects of Henan Province
A Cu+-CP based on the tetranuclear unit {[(HSQPA)(2)Cu-4(bipy)4(]).2H(2)O}n.2nH(2)O has been constructed through Cu2+ salt, 2-(sulfonylquinlium-8-yloxy)phthalic acid (H3(S)QPA), and 4,4'-bipyridine (bipy). This Cu+-CP combined with 2,2,6,6-tetramethylpiperidine-1-oxyl as the cocatalyst is an effective catalyst for aerobic oxidation of alcohols and the synthesis of benzoxazoles and can be recycled at least four times without losing its catalytic activity.
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