期刊
INORGANIC CHEMISTRY
卷 54, 期 19, 页码 9588-9593出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b01687
关键词
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资金
- U.S. DOE, Office of Science, Early Career Research Program [DE-SC0006518]
- Research Corporation for Science Advancement (Cottrell Scholar Award)
- University of Pennsylvania
- U.S. National Science Foundation [ACI-1053575]
The tripodal nitroxide ligand [(2-(BuNO)-Bu-t)C6H4CH2)(3)N](3-) (TriNOx(3-)) binds the Ti(IV) cation and prevents inner-sphere coordination of chloride in the complex [Ti(TriNOx)]Cl (1). The ligand undergoes an eta(2)-NO to kappa(1)-O rearrangement to enable a fluoride ion to bind in the related complex Ti(TriNOx)F (2). Computational and reactivity studies demonstrated that the ligand rearrangement contributed to the enthalpy change in the transfer of a fluoride anion.
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