期刊
INORGANIC CHEMISTRY
卷 54, 期 11, 页码 5139-5141出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b00535
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资金
- National Natural Science Foundation of China [21203140, 21271172]
- Research Fund for the Doctoral Program of Higher Education of China [20130141110008]
- Beijing National Laboratory for Molecular Sciences
Herein, we report the synthesis and postsynthetic modification of a novel alkyne-tagged zirconium metal-organic framework, UiO-68-alkyne. The alkynyl groups in the pore surface were subjected to a click reaction, achieving quantitative conversion and maintaining the crystallinity of the framework.
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