期刊
INORGANIC CHEMISTRY
卷 54, 期 15, 页码 7142-7144出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b01231
关键词
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资金
- Army Research Office [W911NF-13-1-0229]
- Deanship of Scientific Research (DSR), King Abdulaziz University [23-130-36-HiCi]
- DSR
Solvent-assisted linker exchange (SALE) hag recently emerged as an attractive strategy for the synthesis of metal-organic frameworks (MOFs) that are unobtainable via traditional synthetic pathways. Herein we present the first example of selective SALE in which only the benzimiadazolate-containing linkers in a series of mixed-linker zeolitic imidazolate frameworks (ZIF-69, -78, and -76) are replaced. The resultant materials (SALEM-10, SALEM-10b, and SALEM-11, respectively) are isostructural to the parent framework and in each case contain trifluoromethyl moieties. We therefore evaluated each of these materials for their hydrophobicity in condensed and gas phases. We expect that selective SALE will significantly facilitate the design of improved, and potentially complex, MOF materials with new and unusual properties.
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