期刊
ACTA MATERIALIA
卷 59, 期 20, 页码 7498-7507出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.actamat.2011.08.035
关键词
Oxidation; Mechanism; Nanocrystalline films; Zirconium; Time-of-flight secondary ion mass-spectrometry
Two-stage oxidation experiments using O-16 and O-18 isotopes were performed to reveal the governing atomic transport mechanism(s) in thin (thickness <10 nm) oxide films grown during the initial stages of dry thermal oxidation of pure Zr at 450 K. To this end, bare (i.e. without a native oxide) Zr(0001) and Zr(1 0 <(1)over bar> 0) single-crystalline surfaces were prepared under ultra-high vacuum conditions by a cyclic treatment of alternating ion-sputtering and in vacuo annealing steps. Next, the bare Zr surfaces were oxidized at 450 K and at pO(2) = 1 x 10(-4) Pa, first in O-16(2)(g) and subsequently in O-18(2)(g). The O-18-tracer depth distributions in the oxide films were recorded by time-of-flight secondary ion mass spectrometry. It was concluded that the early stage of the oxidation process is governed by oxygen transport to the metal/oxide interface through the lattice and along the grain boundaries of the nanosized oxide grains whereas, on continuing oxidation, only oxygen lattice transport controls the oxidation process. An oxide-film growth mechanism is proposed. (C) 2011 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
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