期刊
ACTA MATERIALIA
卷 59, 期 14, 页码 5692-5699出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.actamat.2011.05.044
关键词
Ni-Mn-Sn ribbons; Martensitic transformation; Melt spinning; Rapid solidification; Phase transition kinetics
资金
- Shanghai Pujiang Program [10PJ1404200]
- Innovative Foundation of Shanghai University of China
- Alexander von Humboldt (AvH) Foundation of Germany
In the present work, the microstructure evolution and kinetics of the martensitic transformation are investigated in as-spun and annealed ribbons of Heusler Ni49Mn39Sn12 using electron microscopy, X-ray diffraction and differential scanning calorimetry. Both ribbons undergo a reversible martensitic transformation during thermal cycling and the low-temperature martensite is confirmed to be a modulated four-layered orthorhombic (4O) structure through in situ cooling transmission electronic microscopy investigation. The annealing effect on the martensitic transformation behavior is discussed from the viewpoints of electron concentration, Mn-Mn inter-atomic distance, atomic order degree and grain size. A strong cooling-rate dependence of phase transition kinetics is found and the mechanism is analyzed. The satisfactory reproducibility obtained during thermal cycling test of this alloy ribbons offers great potential for practical applications. (C) 2011 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
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