期刊
ACTA MATERIALIA
卷 58, 期 5, 页码 1861-1867出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.actamat.2009.11.029
关键词
Implantatiom; Atomic force microscopy; Scanning electron microscopy; X-ray diffraction; Elastomeric polymers
Elastomer films with three-dimensional features self-organized into coherent and semi-coherent buckling domains were created by implanting different species of metal ions and combinations thereof, using a metal evaporation ion Source, into quality polydimethylsiloxane films. As a result of the implantation process, functionalized discrete regions of strain-induced surface buckling were created, taking the forms of domains of parallel surface waves, semi-ordered regions and disordered regions. In addition, deep, strain-induced, V-shaped cracks were observed to penetrate well into the elastomer matrix. Characterization was via optical microscopy, X-ray diffraction, atomic force microscopy and high-resolution scanning electron microscopy (SEM) in the form of field emission SEM. It was found that controlling the localized strain by altering the metal ion species can control the frequency of the V-shaped cracks and the properties of the buckled areas. These observations and possible mechanisms for the formation of the cracks and domains Lire discussed in this paper. (C) 2009 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
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