期刊
ACTA MATERIALIA
卷 58, 期 10, 页码 3664-3675出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.actamat.2010.03.002
关键词
Al-Fe-Ni melt; Diffusion; Atomic mobility; Microstructure; Solidification
资金
- Chinesisch-Deutsches Zentrum fur Wissenschaftsforderung [GZ522]
- National Natural Science Foundation of China [50721003, 50831007]
- Minister of Education of China
A systematical investigation of the diffusivities in an Al-Fe-Ni melt was presented. Based on the experimental and theoretical data about diffusivities, the temperature- and composition-dependent atomic mobilities were evaluated for the elements in Al-Ni, Al-Fe, Fe-Ni and Al-Fe-Ni melts via an effective approach. Most of the reported diffusivities can be reproduced well by the obtained atomic mobilities. In particular, for the first time the ternary diffusivity of the liquid in a ternary system is described in conjunction with the established atomic mobilities. The effect of the atomic mobilities in a liquid on microstructure and microsegregation during solidification was demonstrated with one Al-Ni binary alloy. The simulation results indicate that accurate databases of mobilities in the liquid phase are much needed for the quantitative simulation of microstructural evolution during solidification by using various approaches, including DIC-TRA and the phase-field method. (C) 2010 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
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