期刊
ACTA MATERIALIA
卷 57, 期 15, 页码 4332-4352出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.actamat.2009.05.034
关键词
Martensitic phase transformation; Hysteresis; Nucleation and growth; Nickel-titanium alloys; Continuum mechanics
资金
- ARO-MURI [W91INF-07-1-0410]
- MULTIMAT RTN network [MRTN-CT-2004-505226]
- AFOSR [GRT00008581/ RF60012388]
- DOE [DE-FG02-05ER25706]
- NSF-NIRT [DMS-0304326]
- ONR-MURI [N000140610530]
- NIH [Z196601]
- Humboldt Foundation
We report results from a systematic program of alloy development in the system TiNiX, X = Cu, Pt, Pd, Au, to pursue certain special lattice parameters that have been identified previously with low hysteresis. We achieve lambda(2) = 1, where lambda(2) is the middle eigenvalue of the transformation stretch matrix, for alloys with X = Pt, Pd, Au. In all cases there is a sharp drop in the graph of hysteresis vs. composition at the composition where; lambda(2) = 1. When the size of the hysteresis is replotted vs. lambda(2) we obtain a universal graph for these alloys. Motivated by these experimental results, we present a new theory for the size of the hysteresis based on the growth from a small scale of fully developed austenite martensite needles. The energy of the transition layer plays a critical role in this theory. Overall, the results point to a simple systematic method of achieving low hysteresis and a high degree of reversibility in transforming materials. (C) 2009 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
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