期刊
ACS APPLIED MATERIALS & INTERFACES
卷 7, 期 38, 页码 21511-21520出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.5b06708
关键词
oxygen electrocatalysts; iron carbide; graphitic layers; oxygen reduction reaction; oxygen evolution reaction
资金
- National Natural Science Foundation of China [21176083, 21471056, 21236003, 21206042]
- Basic Research Program of Shanghai [13NM1400700, 13NM1400701]
- Fundamental Research Funds for the Central Universities
It is highly crucial and challenging to develop bifunctional oxygen electrocatalysts for oxygen reduction reactions (ORRs) and oxygen evolution reactions (OERs) in rechargeable metal-air batteries and unitized regenerative fuel cells (URFCs). Herein, a facile and cost-effective strategy is developed to prepare mesoporous Fe-N-doped graphene-like carbon architectures with uniform Fe3C nanoparticles encapsulated in graphitic layers (Fe3C@NG) via a one-step solid-state thermal reaction. The optimized Fe3C@NG800-0.2 catalyst shows comparable ORR activity with the state-of-the-art Pt/C catalyst and OER activity with the benchmarking RuO2 catalyst. The oxygen electrode activity parameter Delta E (the criteria for judging the overall catalytic activity of bifunctional electrocatalysts) value for Fe3C@NG800-0.2 is 0.780 V, which surpasses those of Pt/C and RO2 catalysts as well as those of most nonprecious metal catalysts. Significantly, excellent long-term catalytic durability holds great promise in fields of rechargeable metal-air batteries and URFCs.
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