期刊
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN
卷 118, 期 1384, 页码 1159-1162出版社
CERAMIC SOC JAPAN-NIPPON SERAMIKKUSU KYOKAI
DOI: 10.2109/jcersj2.118.1159
关键词
Glass-ceramics; Solid-electrolyte; Lithium-ion conductor; NASICON
We have developed the high ionic conducting glass-ceramics with the crystalline phase of Li1+x+yAlx(Ti2-yGey)P3-zSizO12 with the NASICON type structure. This type of glass-ceramics exhibits high lithium-ion conductivity of 10(-4) S cm(-1) or more at room temperature. Although this glass-ceramics reacts with Li metal gradually with the passage of time, we have improved the thermal and electrochemical properties by controlling constitution of Ti and Ge in the Li-ion conducting glass-ceramics with the NASICON type structure. Those glass-ceramics worked well as electrolyte of a lithium-ion secondary battery by the charge-discharge test using a half cell with LiFePO4 cathode at room temperature. (C) 2010 The Ceramic Society of Japan. All rights reserved.
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