期刊
ACTA PHYSICO-CHIMICA SINICA
卷 27, 期 2, 页码 479-485出版社
PEKING UNIV PRESS
DOI: 10.3866/PKU.WHXB20110221
关键词
Supercapacitor; Activated carbon; Electrolyte concentration; Temperature
资金
- Dalian Institute of Chemical Physics, Chinese Academy of Sciences, China
The influences of electrolyte concentration and temperature on the capacitive behavior of activated carbon (AC) were investigated by cyclic voltammetry, electrochemical impedance spectroscopy, and galvanostatic charge/discharge measurements. The performance of a symmetric capacitor was characterized in 0.1, 0.5, 1.0, and 6.0 mol . L-1 KOH solution. We found that the high electrolyte concentration led to high capacitance, low internal resistance, and a narrow voltage window. The capacitance and internal resistance were found to be linearly dependent on the logarithm of KOH concentration. AC supercapacitor performance was investigated at 20, 40 and 80 degrees C, respectively. We found that elevated temperatures are favorable for an increase in capacitance and for a decrease in internal resistance. However, elevated temperatures increase the capacitance fading rate during long charge/discharge cycling tests.
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