期刊
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
卷 69, 期 -, 页码 I34-+出版社
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S1600536813012427
关键词
-
资金
- National Research Foundation of Korea [2009-0094046, 2010-0013089]
- National Research Foundation of Korea [2013-PAL, 2010-0013089] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Polycrystalline trisodium vanadium(III) nitridotriphosphate, Na3V( PO3) N-3, was prepared by thermal nitridation of a mixture of NaPO3 and V2O5. The title compound is isotypic with Na3Al( PO3) 3N. In the crystal, the P-atom and the three O-atom sites are on general positions, whereas the Na-,V-and N- atom sites are located on threefold rotation axes. The P atom is coordinated by three O atoms and one N atom in form of a slightly distorted tetrahedron. Three PO3N tetrahedra build up a nitridotriphosphate group, (PO3)(3)N, by sharing a common N atom. The Vatom is coordinated by six O atoms in form of a slightly distorted octahedron. The Na (+) ions occupy three crystallographically distinct sites. One Na (+) ion is situated in an irregular polyhedral coordination environment composed of six O atoms and one N atom, while the other two Na (+) cations are surrounded by six and nine O atoms, respectively.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据