期刊
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
卷 67, 期 -, 页码 M876-U588出版社
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S1600536811021040
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资金
- Experimental Center of Linyi University
In the title compound, [Cu(NCS)(C17H20N4)]BF4, the Cu-II ion is five-coordinated by the four N atoms of the tetradentate Schiff base ligand and one N atom of a thiocyanate ligand, thereby forming a square-pyramidal CuN5 ccoordination geometry. The dihedral angle between the pyridine rings of the Schiff base is 55.58 (14)degrees. The F atoms of the tetrafluoridoborate anion are disordered over two sets of sites with occupancies of 0.614 (3) and 0.386 (3). In the crystal, the components are linked by C-H center dot center dot center dot F interactions.
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