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20,23,26,29,32,35,38,41-Octaoxa-5,9,13-triazapentacyclo[15.14.10.13,30.17,11.115,19]tetratetraconta-1,3(42),7,9,11(44),15(43),16,18,30-nonaene-6,12-dione acetone monosolvate

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WILEY-BLACKWELL
DOI: 10.1107/S1600536811051877

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  1. National Natural Science Foundation of China [21072066, 20672038]
  2. Natural Science Foundation of Guangdong Province of China [8151063101000015]

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In the crystal structure of the title compound, C33H39N3O10 center dot-C3H6O, the acetone molecule is encapsulated into the cavity of the cryptand and fixed by two N-H center dot center dot center dot O and one C-H center dot center dot center dot O hydrogen bond. C-H center dot center dot center dot O and C-H center dot center dot center dot N interactions link neighbouring cryptands. The dihedral angles between the pyridine ring and the benzene rings are 86.47 (17) and 85.53 (13)degrees.

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