期刊
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 54, 期 2, 页码 623-632出版社
AMER CHEMICAL SOC
DOI: 10.1021/ie503094r
关键词
-
资金
- National Natural Science Foundation of China [20906063, 21176063, 21376037]
- National High-tech Research and Development Project of China [2012AA03A611]
- Liaoning Natural Science Foundation of China [20102170]
- Program for Liaoning Excellent Talents in University [LJQ2012010]
- State Key Laboratory of Fine Chemicals [KF1107]
Novel catalytic carbon membranes (CCMs) were fabricated by a mixture of phenolic resin and nanosized copper-based catalyst as precursor, through the processes of blending, compressing, molding, and pyrolysis. The thermal stability of precursors was studied by thermogravimetric analysis. The surface morphology, carbon structure, pore structure, and catalytic reduction property of CCMs were characterized. The CCMs were applied to assembly reactors for the reaction of hydrogen production from methanol steam reforming. Comparative study of catalytic performance was made among the reactors of CCMs, traditional fixed bed, and inert carbon membranes. The methanol steam reforming in CCMs was investigated by some crucial operation variables, including reaction time, reactor configuration, streaming mode, space velocity, and molar ratio. Results have shown that the as-synthesized catalyst and CCMs are stable enough to tolerate the present reaction condition for a long life expectancy. Although the carbon matrix is favorable for dispersing and improving the effective exposure of copper-based catalyst to reactant, the distinct pore diffusion in CCMs is notable. The performance reaches 95% for methanol conversion and 92% for hydrogen yield when a CCM-assembled reactor is operated under the condition of two outlet streams, space velocity at 9.6 h(-1), and methanol/steam molar ratio of 1:1.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据