期刊
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
卷 65, 期 -, 页码 M400-U529出版社
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S1600536809007776
关键词
-
资金
- Zhejiang Provincial Natural Science Foundation [Y4080481]
The molecule of the title compound, [NaNi(C18H18N2O4)(ClO4)(CH3OH)], is almost planar, the maximum deviation from the molecular plane being 5.3 (1) angstrom. The Ni2+ ion is N2O2 coordinated by the Schiff base ligand, leading to a slightly distorted square-planar environment. The Na atom is chelated by the four O atoms of the Schiff base ligand and is coordinated by the O atoms of a methanol ligand and a perchlorate anion. The perchlorate ion is disordered over two sites with occupancies 0.723 (12): 0.277 (12).
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