期刊
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
卷 65, 期 -, 页码 M445-U929出版社
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S1600536809010356
关键词
-
资金
- Zhejiang Provincial Natural Science Foundation [Y4080481]
The molecule of the title compound, [CuNa(C18H18N2O4)(ClO4)(CH3OH)], is almost planar with mean deviation of 5.2(8)degrees. The coordination environment of the Cu-II ion is distorted square-planar and it is N2O2-chelated by the 6,60-dimethoxy-2,2'-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolate Schiff base ligand. The Na atom is chelated by the four O atoms of the Schiff base ligand, and coordinated by a methanol molecule and a perchlorate anion. The six-coordinate Na atom adopts a distorted octahedral coordination geometry. The O atoms of the perchlorate anion are disordered over two sites with site-occupancy factors of 0.697 (5) and 0.303 (5). O-H center dot center dot center dot O hydrogen bonding occurs.
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