期刊
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
卷 64, 期 -, 页码 I74-U20出版社
WILEY-BLACKWELL PUBLISHING, INC
DOI: 10.1107/S1600536808032972
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Cerium(III) ultraphosphate, CeP(5)O(14), was synthesized by a high-temperature solution reaction between CeO(2) and NH(4)H(2)PO(4) in a Ce-P molar ratio of 1:12. Colourless crystals of the orthorhombic polymorph were obtained by cooling the melt of the mixture. The structure contains (P(5)O(14))(3-) anionic ribbons linked by distorted CeO(8) polyhedra.
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