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Chlorido(dimethyl sulfoxide-kS)[2-(2-pyridyl)phenyl-k2N,C1]platinum(II)

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BLACKWELL PUBLISHING
DOI: 10.1107/S1600536808030109

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  1. Grant-in-Aid for Scientific Research [17205008]
  2. Grant-in-Aid for Specially Promoted Research [18002016]
  3. Grant-in-Aid for the Global COE Program
  4. Ministry of Education, Culture, Sports, Science, and Technology of Japan

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In the title compound, [Pt(C11H8N)Cl(C2H6OS)], the S atom of dimethyl sulfoxide is trans to the pyridyl N atom [Pt - S = 2.2181 (11) angstrom] and the chlorido ligand is trans to the carbon donor of 2-(2- pyridyl) phenyl [Pt - Cl = 2.4202 (10) angstrom]. The [2( 2- pyridyl) phenyl] platinum(II) unit forms a one- dimensional stack along the c axis with two independent interplanar separations of 3.44 (9) and 3.50 (2) angstrom.

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