期刊
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
卷 65, 期 -, 页码 M488-M490出版社
WILEY-BLACKWELL
DOI: 10.1107/S010827010904668X
关键词
-
The isomorphous title complexes, dichlorido[4-(3,5-dimethyl-4H-1,2,4-triazol-4-yl) benzoic acid-kappa N(1)]zinc(II) dihydrate, [ZnCl(2)(C(11)H(11)N(3)O(2))(2)]center dot 2H(2)O, and dibromido[4-(3,5-dimethyl-4H-1,2,4- triazol-4-yl) benzoic acid-kappa N(1)]zinc(II) dihydrate, [ZnBr(2)(C(11)H(11)N(3)O(2))(2)]center dot 2H(2)O, were synthesized and crystallized by slow evaporation of the solvent from a solution of the ligand and either zinc chloride or zinc bromide, respectively, in water/ethanol. The Zn(II) ions occupy twofold axes in the noncentrosymmetric orthorhombic space group Fdd2. The metal ion is approximately tetrahedrally coordinated by two monodentate triazole groups of the ligands and additionally by two halide ions. The water molecules incorporate the complexes into a three-dimensional framework made up by hydrogen bonds. Furthermore, each complex possesses two hydrogen-bond-donor sites represented by the carboxy groups and two acceptor sites at the noncoordinating N atoms of the triazoles.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据