期刊
CHINESE JOURNAL OF CATALYSIS
卷 32, 期 5, 页码 836-841出版社
SCIENCE PRESS
DOI: 10.1016/S1872-2067(10)60195-7
关键词
nitrogen oxide removal; selective catalytic reduction; activity; nitrogen oxide oxidation ability; mechanism
The mechanism of NH3-selective catalytic reduction (SCR) over a CeO2-WO3 catalyst was investigated by temperature-programmed desorption (TPD) analysis and in situ diffuse reflectance infrared Fourier transform spectroscopy. The active sites were on CeO2, while WO3 greatly enhanced the amount and strength of the surface Bronsted acid sites and the NO oxidation ability. Both NH4+ and coordinated NH3 contributed to the SCR reaction. Bridging nitrate and monodentate nitrate were confirmed as the reactive nitrate species. Under SCR reaction conditions, surface NH4NO3 was formed, which played the role of an important intermediate species. Two different pathways for the SCR reaction were suggested for the CeO2-WO3 catalyst.
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