期刊
JOURNAL OF CHEMICAL SCIENCES
卷 123, 期 2, 页码 139-144出版社
INDIAN ACAD SCIENCES
DOI: 10.1007/s12039-011-0107-2
关键词
Cu-complex; phenalenyl; radical; X-ray crystallography; Henry reaction
资金
- Department of Science and Technology, New Delhi, India [SR/FT/CS-020/2008]
- IISER, Kolkata
- Council of Scientific and Industrial Research (CSIR), New Delhi
We report the synthesis and characterization of the first transition metal complex of a phenalenyl-based ligand. The reaction of Cu(OAc)(2)center dot H2O with 9-N-methylamino-1-N'-methylimino-phenalene (LH) in 1:1 stoichiometric ratio results in the formation of a mononuclear copper complex [LCu(OAc)] (1). The molecular structure of 1 was established by X-ray crystallography. The electrochemistry of 1 indicates the formation of an anionic radical by one electron reduction into the non-bonding molecular orbital of the phenalenyl system. The complex 1 efficiently catalyses the C-C bond forming Henry reaction.
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