期刊
ACS APPLIED MATERIALS & INTERFACES
卷 7, 期 21, 页码 11089-11098出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.5b01188
关键词
donor acceptor-type conjugated polymers; green electrochromics; PEDOT; thiadiazolo[3,4-dpyridine; low bandgap
资金
- National Natural Science Foundation of China [51303073, 51463008]
- Ganpo Outstanding Talents 555 projects
- Training Plan for the Main Subject of Academic Leaders of Jiangxi Province
- Natural Science Foundation of Jiangxi Province [20122BAB216011, 20142BAB216029]
- Science and Technology Landing Plan of Universities in Jiangxi Province [KJLD12081]
- Provincial Projects for Postgraduate Innovation in Jiangxi [YC2014-S441, YC2014-S431]
- Scientific Research Projects of Jiangxi Science & Technology Normal University [2014QNBJRC003]
Thiadiazolo[3,4-c]pyridine (PT), an important analog of benzothiadiazole (BT), has most recently been explored as a novel electron acceptor. It exhibits more electron-accepting ability and other unique properties and potential advantages over BT, thus inspiring us to investigate PT-based donoracceptor-type (DA) conjugated polymer in electrochromics. Herein, PT was employed for the rational design of novel donoracceptor-type systems to yield a neutral green electrochromic polymer poly(4,7-di(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-[1,2,5] thiadiazolo[3,4-c]pyridine) (PEPTE). PEPTE revealed a lower bandgap (E-g,E-ele = 0.85 eV, E-g,E-opt = 1.12 eV) than its BT analog and also favorable redox activity and stability. Furthermore, electrochromic kinetic studies demonstrated that PEPTE displayed higher coloration efficiency than BT analog, good optical memory, and very fast switching time (0.3 s at all three wavelengths), indicating that PT would probably be a promising choice for developing novel neutral green electrochromic polymers by matching with various donor units.
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