期刊
ACS NANO
卷 8, 期 1, 页码 139-152出版社
AMER CHEMICAL SOC
DOI: 10.1021/nn406219x
关键词
supramolecular chemistry; quantum clusters; Au-25; cyclodextrin; inclusion complex
类别
资金
- CSIR
- DST
- Academy of Finland through an Indo-Finland initiative
We present a versatile approach for tuning the surface functionality of an atomically precise 25 atom gold cluster using specific host-guest interactions between beta-cyclodextrin (CD) and the ligand anchored on the cluster. The supramolecular interaction between the Au-25 cluster protected by 4-(t-butyl)benzyl mercaptan, labeled Au25SBB18, and CD yielding Au25SBB18 boolean AND CDn (n = 1, 2, 3, and 4) has been probed experimentally using various spectroscopic techniques and was further analyzed by density functional theory calculations and molecular modeling. The viability of our method in modifying the properties of differently functionalized Au-25 clusters is demonstrated. Besides modifying their optoelectronic properties, the CD moieties present on the cluster surface provide enhanced stability and optical responses which are crucial in view of the potential applications of these systems. Here, the CD molecules act as an umbrella which protects the fragile cluster core from the direct interaction with many destabilizing agents such as metal ions, ligands, and so on. Apart from the inherent biocompatibility of the CD-protected Au clusters, additional capabilities acquired by the supramolecular functionalization make such modified clusters preferred materials for applications, including those in biology.
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