期刊
ACS NANO
卷 7, 期 2, 页码 1646-1651出版社
AMER CHEMICAL SOC
DOI: 10.1021/nn305608a
关键词
metal; graphene; interaction; nanoparticle; interaction energy; gold; platinum; copper
类别
资金
- Grant Agency of the Czech Republic [P208/12/G016]
- Operational Program Research and Development for Innovations-European Regional Development Fund [CZ.1.05/2.1.00/03.0058]
- European Social Fund [CZ.1.07/2.3.00/20.0017]
- Danish National Research Foundation
- Villum Foundation
- Palacky University Olomouc [PrF_2012_028]
- Praemium Academiae of the Academy of Sciences of the Czech Republic
- Villum Fonden [00007194] Funding Source: researchfish
The two-dimensional material graphene has numerous potential applications in nano(opto)electronics, which inevitably involve metal graphene interfaces. Theoretical approaches have been employed to examine metal graphene interfaces, but experimental evidence is currently lacking. Here, we combine atomic force microscopy (AFM) based dynamic force measurements and density functional theory calculations to quantify the interaction between metal-coated AFM tips and graphene under ambient conditions. The results show that copper has the strongest affinity to graphene among the studied metals (Cu, Ag, Au, Pt, Si), which has important implications for the construction of a new generation of electronic devices. Observed differences in the nature of the metal-graphene bonding are well reproduced by the calculations, which included nonlocal Hartree-Fock exchange and van der Waals effects.
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