期刊
ACS NANO
卷 8, 期 1, 页码 113-123出版社
AMER CHEMICAL SOC
DOI: 10.1021/nn404537s
关键词
CdSe/CdS/ZnSe; Type-I/Type-II; dual emission; nanocrystals; C/I/S; SHNS
类别
资金
- DRDO grant [ERIPR/ER/1000389/M/01/1407]
- CSIR
- UGC
Core/intermediate/shell (C/I/S) structures with Type-I emission are well-known and are gaining immense importance due to their superior luminescence properties. Here, we report a unique C/I/S structure composed of CdSe/CdS/ZnSe that exhibits both Type-I and Type-II phenomena. The structures have been well characterized using a combination of optical and structural techniques. The photoluminescence (PL) and photoluminescence excitation (PIE) data indicate the formation of a combined Type-I and Type-II structure in one material, results supported by simple theoretical calculations. Single particle fluorescence reveals colocalization of both the emissions. The X-ray diffraction (XRD) and transmission electron microscopy (TEM) results confirm the structure of these particles. The time-resolved fluorescence studies show the possibility of tuning the lifetime of these materials by changing the Type-I/Type-II thickness ratios. It is possible to form these two separate excitons in the same system separated by a CdS intermediate layer that acts both as a barrier and an active member of the Type-II system allowing the generation and recombination of two excitons, in violation of Kasha's rule.
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