期刊
ACS NANO
卷 5, 期 9, 页码 6791-6818出版社
AMER CHEMICAL SOC
DOI: 10.1021/nn2025397
关键词
noncovalent bond; adaptivity; recycling; nanostructure; recyclable material; adaptive materials; nanomaterials; self-assembly; supramolecular polymer; supramolecular gel; hydrogel; hydrophobic interactions; pathway-dependent self-assembly; noncovalent synthesis; hydrogen bond; supramolecular multivalency; stimuli-responsive materials; supramolecular reaction; ionic self-assembly; complexity; noncovalent network; host-guest interactions; kinetic control; self-assembly mechanism; nonequilibrium self-assembly; nanoparticles; nanoparticle assembly
类别
资金
- Gerhardt M. J. Schmidt Minerva Center for Supramolecular Architectures, Israel Science Foundation
- Helen and Martin Kimmel Center for Molecular Design
Noncovalent systems are adaptive and allow facile processing and recycling. Can they be at the same time robust? How can one rationally design such systems? Can they compete with high-performance covalent materials? The recent literature reveals that noncovalent systems can be robust yet adaptive, self-healing, and recyclable, featuring complex nanoscale structures and unique functions. We review such systems, focusing on the rational design of strong noncovalent interactions, kinetically controlled pathway-dependent processes, complexity, and function. The overview of the recent examples points at the emergent field of noncovalent nanomaterials that can represent a versatile, multifunctional, and environmentally friendly alternative to conventional covalent systems.
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