期刊
ACS NANO
卷 5, 期 9, 页码 7198-7204出版社
AMER CHEMICAL SOC
DOI: 10.1021/nn202012m
关键词
graphene; acetylene; cobalt; transistor; mobility
类别
资金
- NRI-SWAN
- DARPA [FA8650-08-C-7838]
- IBM-UT [W0853811]
- Robert Noyce Memorial Fellowship
- Cockrell School of Engineering
- NSF-IGERT [DGE-0549417]
We demonstrate the synthesis of large-area graphene on Co, a complementary metal-oxide-semiconductor (CMOS)-compatible metal, using acetylene (C(2)H(2)) as a precursor in a chemical vapor deposition (CVD)-based method. Cobalt films were deposited on SiO(2)/Si, and the influence of Co film thickness on monolayer graphene growth was studied, based on the solubility of C in Co. The surface area coverage of monolayer graphene was observed to increase with decreasing Co film thickness. A thorough Raman spectroscopic analysis reveals that graphene films, grown on an optimized Co film thickness, are principally composed of monolayer graphene. Transport properties of monolayer graphene films were investigated by fabrication of back-gated graphene field-effect transistors (GFETs), which exhibited high hole and electron mobility of similar to 1600 cm(2)/V s and similar to 1000 cm(2)/V s, respectively, and a low trap density of similar to 1.2 x 10(11) cm(-2).
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