期刊
ACS NANO
卷 4, 期 5, 页码 2713-2720出版社
AMER CHEMICAL SOC
DOI: 10.1021/nn100343f
关键词
transparent; conductor; electrode; graphene; figure of merit
类别
资金
- Science Foundation Ireland (SFI) [03/CE3/M406s1]
From published transmittance and sheet resistance data, we have calculated a figure of merit for transparent, conducting graphene films; the DC to optical conductivity ratio, sigma(DC)-sigma(Op). For most reported results, this conductivity ratio clusters around the values sigma(DC)-sigma(Op) = 0.7, 4.5, and 11. We show that these represent fundamental limiting values for networks of graphene flakes, undoped graphene stacks, and graphite films, respectively. The limiting value for graphene flake networks is much too low for transparent-electrode applications. For graphite, a conductivity ratio of 11 gives R-s = 377 Omega/square for T = 90%, far short of the 10 Omega/square minimum requirement for transparent conductors in current driven applications. However, we suggest that substrate-induced doping can potentially increase the 2-dimensional DC conductivity enough to make graphene a viable transparent conductor. We show that four randomly stacked graphene layers can display T approximate to 90% and 10 Omega/square if the product of carrier density and mobility reaches n mu = 1.3 x 10(17) V-1 s(-1). Given achieved doping values and attainable mobilities, this is just possible, resulting in potential values of sigma(DC)-sigma(Op) of up to 330. This is high enough for any transparent conductor application.
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