期刊
ACS NANO
卷 4, 期 10, 页码 5679-5684出版社
AMER CHEMICAL SOC
DOI: 10.1021/nn101282w
关键词
ZnO nanowire; dye-sensitized solar cell; electrospinning; nanofibers; nanofilms; light-scattering layer
类别
资金
- National Science Council [NSC 96-2628-E006-017-MY3]
- Bureau of Energy, Ministry of Economic Affairs in Taiwan [98-D0204-2]
A 74% enrichment of the efficiency of ZnO nanowire (NW) dye-sensitized solar cells (DSSCs) is achieved by the addition of a novel light-scattering nanocrystalline film (nanofilm). The 100 nm thick nanofilm is derived from the polyvinylpyrrolidone-hosted SnO2/ZnO nanofibers electrospun on the top of ZnO NW arrays via methanol vapor treatment followed by high-temperature calcination. Structural characterizations show that the film is composed of SnO2 and ZnO nanocrystals with a diameter of 10 nm. Short-circuit current, open-circuit voltage, and fill factor of the nanofilm/ZnO NW DSSCs are all superior to those of the ZnO NW DSSCs. The mechanism of photocurrent enhancement in the nanofilm/ZnO NW DSSCs has been investigated using optical modulation spectroscopy. Intensity modulation photocurrent spectroscopy (IMPS) measurements reveal that the dye-sensitized nanofilm does not contribute significant photocurrent in the nanofilm/ZnO NW DSSCs. The significant enhancement of the efficiency of the ZnO NW DSSCs is achieved by reflecting unabsorbed photons back into the NW anode using the novel light-scattering layer of nanofilm.
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