期刊
ACS NANO
卷 3, 期 10, 页码 3315-3325出版社
AMER CHEMICAL SOC
DOI: 10.1021/nn901002q
关键词
nanoskiving; nanowires; nanofabrication; conjugated polymers; microtome; nanophotonics; nanowire positioning; magnetic positioning
类别
资金
- National Science Foundation [CHE-0518055]
- NSF under NSEC [PHY-0117795, PHY-0646094]
- MRSEC [DMR-0213805, DMR-0820484]
- National Science Foundation under NSF [ECS-0335765]
- American Chemical Society, Division of Organic Chemistry
- Novartis
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [GRANTS:13883333, 0820484] Funding Source: National Science Foundation
This paper describes a process for the fabrication and positioning of nanowires (of Au, Pd, and conjugated polymers) embedded in thin epoxy slabs. The procedure has four steps: (i) coembedding a thin film of metal or conducting polymer with a thin film of nickel metal (Ni) in epoxy; (ii) sectioning the embedded structures into nanowires with an ultramicrotome (nanoskiving); (iii) floating the epoxy sections on a pool of water; and (iv) positioning the sections with an external magnet to a desired location (magnetic mooring). As the water evaporates, capillary interactions cause the sections to adhere to the substrate. Both the Ni and epoxy can be etched to generate free-standing metallic nanowires. The average translational deviation In the positioning of two nanowires with respect to each other is 16 +/- 13 mu m, and the average angular deviation is 3 +/- 2 degrees. Successive depositions of nanowires yield the following structures of interest for electronic and photonic applications: electrically continuous junctions of two Au nanowires, two Au nanowires spanned by a poly(3-hexylthiophene) (P3HT) nanowire; single-crystalline Au nanowires that cross; crossbar arrays of Au nanowires; crossbar arrays of Au and Pd nanowires; and a 50 x 50 array of poly(benzimidazobenzophenanthroline ladder) (BBL) nanowires. Single-crystalline Au nanowires can be placed on glass wool fibers or on microfabricated polymeric waveguides, with which the nanowire can be addressed optically.
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