期刊
ACS APPLIED MATERIALS & INTERFACES
卷 10, 期 36, 页码 30852-30859出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.8b09749
关键词
bioinspired; nanochannel; nitrite ion; acid and light activation; harmless conversion
资金
- National Key Research and Development Program of China [2017YFA0206904, 2017YFA0206900]
- National Natural Science Foundation [21625303, 21374088, 51673206, 21434003, 91427303]
- Fundamental Research Funds for the Central Universities [3102017jc03006, 3102017jc01001]
- Key Research Program of the Chinese Academy of Sciences [QYZDY-SSW-SLH014]
Inspired by the delicate functions of living organisms to transport or transform nitrite ions (NO2-), a bioinspired smart nanochannel that can realize harmless conversion of NO2- into N-2 is developed by immobilizing a NO2--responsive functional molecule, p-phenylenediamine, onto a single conical polyethylene terephthalate nanochannel. Subsequently, the aromatic primary amine groups could be triggered to transform into a phenyldiazonium molecule based on the acid-activated NO2--binding process. The nanochannel exhibits specific selectivity and highly ultratrace recognition of NO2-. Fascinatingly, the transformed phenyldiazonium molecules could be triggered to generate phenol groups and release N-2 by ultraviolet light activation, achieving NO2- harmless conversion. This system could provide inspiration to construct artificial nanofluidic devices for ion-sensing and nitrogen cycle fields.
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