期刊
ACS APPLIED MATERIALS & INTERFACES
卷 6, 期 3, 页码 1773-1780出版社
AMER CHEMICAL SOC
DOI: 10.1021/am404765y
关键词
flower-shaped microspheres; microwave-assisted; binary metal oxides; supercapacitor
资金
- Natural Science Foundation of China [21177090, 21275104, 21175094]
Binary metal oxides with three-dimensional (3D) superstructure have been regarded as desirable electrode materials for the supercapacitor due to the combination of the improved electrical conductivity and effective porous structure. 3D hierarchical flower-shaped nickel cobaltite (NiCo2O4) microspheres have been fabricated by a rapid and template-free microwave-assisted heating (MAH) reflux approach followed by pyrolysis of the as-prepared precursors. The flower-shaped NiCo2O4 microspheres, composed of ultrathin nanopetals with thickness of about 15 nm, are endowed with large specific surface area (148.5 m(2) g(-1)) and a narrow pore size distribution (5-10 nm). The as-fabricated porous flower-shaped NiCo2O4 microspheres as electrode materials for supercapacitor exhibited high specific capacitance of 1006 F g(-1) at 1 A g(-1), enhanced rate capability, and excellent electrochemical stability with 93.2% retention after 1000 continuous charge-discharge (CD) cycles even at a high current density of 8 A g(-1). The desirable integrated performance enables it to be a promising electrode material for the electrochemical supercapacitor (EC).
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