期刊
ACS APPLIED MATERIALS & INTERFACES
卷 6, 期 11, 页码 8434-8440出版社
AMER CHEMICAL SOC
DOI: 10.1021/am501319v
关键词
graphitic carbon nitride; morphology-preserving; nanorod; photocatalytic; enzymatic; NADH regeneration
资金
- Alexander von Humboldt Foundation
- National Natural Science Foundation of China [21103095, 51102163]
- Excellent Young Scientific Research Talents in University of Fujian, China [JA12285]
Uniform graphitic carbon nitride nanorods (CNR) were facilely obtained by a morphology-preserving strategy by templating a chiral mesostructured silica nanorod. The hexagonal mesostructured pore structures of one-dimensional silica nanorods can provide nanoconfinement space for carbon nitride condensation to perfect layered structures. CNR demonstrated excellent photocatalytic capability in generating hydrogen from water even with a small specific surface area, compared with its mesoporous counterpart. For further application demonstration, the CNR was used for photocatalytic regeneration of NAD(+) to NADH, the biological form of hydrogen. The in situ NADH regeneration system was further coupled with L-glutamate dehydrogenase for sustainable generation of L-glutamate from alpha-ketoglutarate. The high yield and high efficiency obtained here point a high-throughput and sustainable way for practical enzymatic applications.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据