期刊
ACS APPLIED MATERIALS & INTERFACES
卷 6, 期 24, 页码 22871-22875出版社
AMER CHEMICAL SOC
DOI: 10.1021/am5071317
关键词
cobalt imidazolate framework; gas sensor; selectivity; trimethylamine
资金
- 973 program [2012CB821705, 2011CB932504]
- NSFC [91222105, 21221001]
- CAS [XDA07070200]
A cobalt imidazolate (im) framework material [Co(im)(2)](n) was employed to use as a trimethylamine (TMA) gas sensor and the [Co(im)(2)](n) sensor can be easily fabricated by using Ag-Pd interdigitated electrodes. Gas sensing measurement indicated that the [Co(im)(2)](n) sensor shows excellent selectivity, high gas response and a low detection limit level of 2 ppm to TMA at 75 degrees C. The good selectivity and high response to TMA of the sensor based on [Co(im)(2)](n) may be attributed to the weak interaction between the TMA molecules and the [Co(im)(2)](n) framework. That may provide an ideal candidate for detecting freshness of fish and seafood.
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