4.8 Article

Highly Selective and Sensitive Trimethylamine Gas Sensor Based on Cobalt Imidazolate Framework Material

期刊

ACS APPLIED MATERIALS & INTERFACES
卷 6, 期 24, 页码 22871-22875

出版社

AMER CHEMICAL SOC
DOI: 10.1021/am5071317

关键词

cobalt imidazolate framework; gas sensor; selectivity; trimethylamine

资金

  1. 973 program [2012CB821705, 2011CB932504]
  2. NSFC [91222105, 21221001]
  3. CAS [XDA07070200]

向作者/读者索取更多资源

A cobalt imidazolate (im) framework material [Co(im)(2)](n) was employed to use as a trimethylamine (TMA) gas sensor and the [Co(im)(2)](n) sensor can be easily fabricated by using Ag-Pd interdigitated electrodes. Gas sensing measurement indicated that the [Co(im)(2)](n) sensor shows excellent selectivity, high gas response and a low detection limit level of 2 ppm to TMA at 75 degrees C. The good selectivity and high response to TMA of the sensor based on [Co(im)(2)](n) may be attributed to the weak interaction between the TMA molecules and the [Co(im)(2)](n) framework. That may provide an ideal candidate for detecting freshness of fish and seafood.

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