期刊
ACS APPLIED MATERIALS & INTERFACES
卷 6, 期 21, 页码 19176-19183出版社
AMER CHEMICAL SOC
DOI: 10.1021/am504971h
关键词
liquid liquid interface; anatase TiO2; ultrathin nanosheets; {001} facet; lithium-ion batteries
资金
- National Natural Science Foundation of China [21173084]
- Large Instruments Open Foundation of East China Normal University
An interface between toluene and water was utilized to synthesize ca. 10 nm thick of anatase TiO2 nanosheets (NSs) with 82% exposure of {001} facets. In this procedure, highly corrosive and toxic HF, which was generally used to prepare TiO2 NSs with largely exposed high energy facets, was avoided. Furthermore, the surfaces of the NSs were quite clean as suggested by XPS analysis. Serving as anode materials in lithium-ion batteries, these as-prepared anatase TiO2 NSs manifested a low initial irreversible capacity loss (12.5% at 1 C), an excellent capacity retention at 10 C charge discharge rate (101.9 mA h after 100 cycles), and enhanced rate performance at 0.5-10 C current rates in compared with Degussa P25 TiO2 nanoparticles (NPs). Their excellent electrochemical performances were mainly derived from the large proportion of {001} exposed facets and a very short diffusion pathway, which allowed fast and efficient Li+ transportation in the electrodes.
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