4.8 Article

Advance in Novel Boron Nitride Nanosheets to Nanoelectronic Device Applications

期刊

ACS APPLIED MATERIALS & INTERFACES
卷 5, 期 11, 页码 5051-5056

出版社

AMER CHEMICAL SOC
DOI: 10.1021/am400871s

关键词

synthesis; BNNSs; doping; Schottky diode; sensor

资金

  1. NASA-EPSCoR [NNX13AB22A, NNX07AO30A]
  2. DoD
  3. NSF [1002410]
  4. UPR-DEGI
  5. Office of Integrative Activities
  6. Office Of The Director [1002410] Funding Source: National Science Foundation

向作者/读者索取更多资源

We report low-temperature synthesis of large-scale boron nitride nanosheets (BNNSs) and their applications for high-performance Schottky diode and gas sensor. Ten minutes of synthesis with a short-pulse-laser-produced plasma deposition technique yields a large amount of highly flat, transparent BNNSs. A basic reason for using short-pulse plasma beams is to avoid nanosheet thermal ablation or have low heat generated. Consequently, it greatly reduces the stress and yield large, flat BNNSs. The average size of obtained BNNS is around 10 mu m and thickness is around 1.7 nm. Carbon element has been used for doping BNNSs and achieving BNNSs-based Schottky diode and gas sensing device. Typical current versus voltage characteristics of diode are examined. The breakdown reverse voltage is around -70 V. This probably indicates that the breakdown electric field of BNNSs-base diode is up to 1 x 10(8) V/cm. Sensing behavior of BNNSs-based gas sensor toward methane diluted with dry air is also characterized The response time and recovery time are around 3 and 5 s at the operating temperature of 150 degrees C. Relatively, the sensor has poor sensitivity to oxygen gas.

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