期刊
ACS APPLIED MATERIALS & INTERFACES
卷 5, 期 5, 页码 1811-1817出版社
AMER CHEMICAL SOC
DOI: 10.1021/am303165e
关键词
superhydrophobic; thiol-ene; photopolymerization; spray-deposition; water repellent
资金
- National Science Foundation [NSF SCIART DMR-1041853, NSF CAREER DMR-1056817]
- US Dept. of Education GAANN Fellowship Program [P200A090066]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1041853] Funding Source: National Science Foundation
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1056817] Funding Source: National Science Foundation
We report a simple and versatile method for the fabrication of superhydrophobic inorganic-organic thiol-ene coatings via sequential spray-deposition and photopolymerization under ambient conditions. The coatings are obtained by spray-deposition of UV-curable hybrid inorganic-organic thiol-ene resins consisting of pentaerythritol tetra(3-mercaptopropionate) (PETMP), triallyl isocyanurate (TTT), 2,4,6,8-tetramethyl-2,4,6,8-tetravinylcyclotetrasiloxane (TMTVSi), and hydrophobic fumed silica nanoparticles. The spray-deposition process and nanoparticle agglomeration/dispersion provide surfaces with hierarchical morphologies exhibiting both micro- and nanoscale roughness. The wetting behavior, dependent on the concentration of TMTVSi and hydrophobic silica nanoparticles, can be varied over a broad range to ultimately provide coatings with high static water contact angles (>150 degrees), low contact angle hysteresis, and low roll off angles (<5 degrees). The cross-linked thiol-ene coatings are solvent resistant, stable at low and high pH, and maintain superhydrophobic wetting behavior after extended exposure to elevated temperatures We demonstrate the versatility of the spray-deposition and UV-cure process on a variety of substrate surfaces including glass, paper, stone, and cotton fabric.
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