期刊
ACS APPLIED MATERIALS & INTERFACES
卷 6, 期 1, 页码 137-142出版社
AMER CHEMICAL SOC
DOI: 10.1021/am403643x
关键词
NiO/Ni/graphene; nanocomposites; electrical wire explosion; Li ion battery
资金
- National Research Foundation of Korea (NRF)
- Ministry of Science, ICT, and Future Planning [2012M1A2A2671802, 2012R1A2A2A01 045382]
NiO/Ni/graphene nanocomposites were prepared using a simple and environmentally friendly method comprising an electrical wire pulse technique in oleic acid containing graphenes and subsequent annealing to form anodes for Li ion batteries. The control product of NiO/Ni nanocomposite was prepared under the same conditions and characterized by structural and electrochemical analysis. The obtained NiO/Ni/graphene nanocomposite particles had sizes of 5-12 nm and a high surface area of 137 m(2) g(-1). In comparison to NiO/Ni, NiO/Ni/graphene exhibited improved cycling performance and good rate capability. Reversible capacity was maintained at over 600 mA h g(-1) at 0.2 C and was attributed to the alleviation in volume change and improved electrical conductivity of NiO/Ni/graphehe nanocomposites.
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