期刊
ACS APPLIED MATERIALS & INTERFACES
卷 5, 期 4, 页码 1333-1341出版社
AMER CHEMICAL SOC
DOI: 10.1021/am3026129
关键词
lithium-air; Li anode; photoelectron spectroscopy; synchrotron; XPS; oxygen battery; lithium perchlorate; lithium bis(oxalato) borate
资金
- Swedish Energy Agency (STEM)
- Swedish Research Council (VR)
- StandUp for Energy
The surface compositions of a MnO2 catalyst containing carbon cathode and a Li anode in a Li-O-2 battery were investigated using synchrotron-based photoelectron spectroscopy (PES). Electrolytes comprising LiClO4 or LiBOB salts in PC or EC:DEC (1:1) solvents were used for this study. Decomposition products from LiClO4 or LiBOB were observed on the cathode surface when using PC. However, no degradation of LiClO4 was detected when using EC/DEC. We have demonstrated that both PC and EC/DEC solvents decompose during the cell cycling to form carbonate and ether containing compounds on the surface of the carbon cathode. However, EC/DEC decomposed to a lesser degree compared to PC. PES revealed that a surface layer with a thickness of at least 1-2 nm remained on the MnO2 catalyst at the end of the charged state. It was shown that the detachment of Kynar binder influences the surface composition of both the carbon cathode and the Li anode of Li-O-2 cells. The PES results indicated that in the charged state the SEI on the Li anode is composed of PEO, carboxylates, carbonates, and LiClO4 salt.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据