期刊
ACS APPLIED MATERIALS & INTERFACES
卷 5, 期 19, 页码 9405-9410出版社
AMER CHEMICAL SOC
DOI: 10.1021/am4029872
关键词
segmented microfluidics; continuous synthesis; metal-organic framework; dicarboxylate; MIL-88B
资金
- Spanish Ministry of Economy and Competitiveness [MAT2010-15870]
- Aragon Government
- ESF
- People Program (Marie Curie Actions) of the EU under REA grant [321642]
Segmented microfluidics was applied to the ultrafast crystallization of dicarboxylate based MIL-88B type metal-organic frameworks (MOFs; Fe-MIL-88B-NH2, Fe-MIL-88B, and Fe-MIL-88B-Br). Particular attention was paid to the influence of the temperature, residence time, and slug volume on the size and crystal size distribution of the MOFs. Average sizes in the 90-900 nm range with relatively narrow crystal size distributions were obtained with residence times as short as 20 s depending on the MOF type and synthesis conditions.
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