期刊
ACS APPLIED MATERIALS & INTERFACES
卷 4, 期 3, 页码 1164-1168出版社
AMER CHEMICAL SOC
DOI: 10.1021/am201825t
关键词
organic solar cell; high work-function materials; sol-gel metal oxides; transition metal oxides; stability; PEDOT:PSS
资金
- German Federal Ministry for Education and Research [FKZ 13N11777]
Sol-gel processed MoOx (sMoO(x)) hole-extraction layers for organic solar cells are reported. A Bis(2,4-pentanedionato)molybdenum(VI)dioxide/isopropanol solution is used and only a moderate thermal post deposition treatment at 150 degrees C in N-2 ambient is required to achieve sMoO(x) layers with a high work-function of 5.3 eV. We demonstrate that in P3HT:PC60BM organic solar cells (OSCs) our sMoO(x) layers lead to a high filling factor of about 65% and an efficiency of 3.3% comparable to that of reference devices with thermally evaporated MoO3 layers (eMoO(3)). At the same time, a substantially improved stability of the OSCs compared to devices using a PEDOT:PSS hole extraction layer is evidenced.
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