期刊
ACS APPLIED MATERIALS & INTERFACES
卷 4, 期 4, 页码 2018-2024出版社
AMER CHEMICAL SOC
DOI: 10.1021/am201860r
关键词
sputtering deposition; electrospinning; Pd; catalysis; oxygen reduction reaction; methanol tolerant; direct methanol fuel cells
资金
- NASA-URC [NNX10AQ17A]
- NASA [NNG056678H]
- Department of Energy [DE-FG02-08ER46526]
- NSF-EPSCoR Institute for Functional Nanomaterials [OIA-0701525, EPS-1002410]
- U.S. Department of Energy (DOE) [DE-FG02-08ER46526] Funding Source: U.S. Department of Energy (DOE)
- Office Of The Director
- Office of Integrative Activities [1002410] Funding Source: National Science Foundation
A novel approach for the synthesis of palladium (Pd) nanoshells on highly ordered pyrolytic graphite (HOPG) surfaces for the oxygen reduction reaction (ORR) is described. Magnetron sputtering deposition was used to synthesize Pd thin films and nanoshells of different thicknesses on HOPG surfaces. Electrospun polymer fibers mats of poly(ethylene) oxide (PEO) were used as templates for the Pd nanoshells formation. The palladium thicknesses between 25 and 95 nm were deposited by magnetron sputtering. Scanning electron microscopy and energy-dispersive X-ray fluorescence spectroscopy were used to study the morphology and composition of the Pd nanoshells. Electrocatalytic activity toward the ORR and methanol tolerance in oxygen saturated 0.5 M H2SO4 solution was determined. Palladium nanoshells presented higher electrocatalytic activity toward ORR than Pd thin films of similar electrodes thicknesses and geometric area. Since palladium has higher methanol tolerance than platinum, the Pd nanoshells are promising electrode materials for direct methanol fuel cells (DMFC).
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