期刊
ACS APPLIED MATERIALS & INTERFACES
卷 4, 期 6, 页码 3239-3246出版社
AMER CHEMICAL SOC
DOI: 10.1021/am300593k
关键词
graphene-based materials; supercapacitor; thermal treatment; surface modification
资金
- Oak Ridge National Laboratory
- Oak Ridge National Laboratory by the Division of Scientific User Facilities, U.S. Department of Energy
- ORISE/ORNL postdoctoral program
Graphene materials were synthesized by reduction of exfoliated graphite oxide and then thermally treated in nitrogen to improve the surface area and their electrochemical performance as electrical double-layer capacitor electrodes. The structural and surface properties of the prepared reduced graphite oxide (RGO) were investigated using atomic force microscopy, scanning electron microscopy, Raman spectra, X-ray diffraction pattern analysis, and nitrogen adsorption/desorption studies. RGO forms a continuous network of crumpled sheets, which consist of large amounts of few-layer and single-layer graphenes. Electrochemical studies were conducted by cyclic voltammetry, impedance spectroscopy, and galvanostatic charge-discharge measurements. The modified RGO materials showed enhanced electrochemical performance, with maximum specific capacitance of 96 F/g, energy density of 12.8 Wh/kg, and power density of 160 kW/kg. These results demonstrate that thermal treatment of RGO at selected conditions is a convenient and efficient method for improving its specific capacitance, energy, and power density.
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