期刊
ACS APPLIED MATERIALS & INTERFACES
卷 4, 期 2, 页码 791-795出版社
AMER CHEMICAL SOC
DOI: 10.1021/am201427q
关键词
ionic liquids; ionic liquid precursors; tetrabutylammonium hydroxide; nanoparticles; CuO; gas sensing
资金
- Deutsche Forschungsgemeinschaft [TA571/2-1, 3-1, 7-1]
- University of Potsdam
- MPI of Colloids and Interfaces (Colloid Chemistry Department)
The sensing potential of CuO nanoparticles synthesized via. precipitation from a water/ionic liquid precursor (ILP) mixture was investigated. The particles have a moderate surface area of 66 m(2)/g after synthesis, which decreases upon thermal treatment to below 5 m(2)/g. Transmission electron microscopy confirms crystal growth upon annealing, likely due to sintering effects. The as-synthesized particles can be used for ethanol sensing. The respective sensors show fast response and recovery times of below 10 s and responses greater than 2.3 at 100 ppm of ethanol at 200 degrees C, which is higher than any CuO-based ethanol sensor described so far.
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