期刊
ACS APPLIED MATERIALS & INTERFACES
卷 4, 期 8, 页码 4237-4245出版社
AMER CHEMICAL SOC
DOI: 10.1021/am300946f
关键词
bipolar resistive switching; Al electrode; fuel-assisted deposition; nickel oxide; interfacial reaction; oxygen reservoir
资金
- National Science Council of Taiwan [NSC-101-3113-E-006-002, NSC-100-2628-E-006-026-MY3]
Bipolar resistive switching in Al/fuel-assisted NiOx (40 nm)/ITO devices is demonstrated in this work. XPS analysis reveals the simultaneous presence of metallic Ni, Ni2O3, and NiO components in the fuel-assisted NiOx. The concentration, as well as spreading of the metallic Ni and accompanying oxygen vacancies, are related to the Al/NiOx interfacial reaction, which is enhanced by the increasing thickness of the Al top electrode. Correspondingly, the preswitching-on voltage decreases while the preswitching-off voltage increases with increasing thickness (from 15 to 60 nm) of Al. However, in regular switching operation, set and reset voltages are considerably lowered for devices with an increased thickness of the Al top electrode. The bipolar resistive switching behaviors of Al/fiiel-assisted NiOx/ITO devices are therefore discussed based on the formation of conductive paths and their correlation with the Al-electrode modulated composition in the fuel assisted NiOx. The Al/NiOx interfacial reaction region pairs with ITO to form a dual-oxygen-reservoir structure. Mechanisms of construction/destruction of conducting paths originating from the electrochemical redox reactions at the interface between NiOx, and the dual oxygen reservoirs will also be explicated.
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