期刊
ACS APPLIED MATERIALS & INTERFACES
卷 4, 期 3, 页码 1233-1238出版社
AMER CHEMICAL SOC
DOI: 10.1021/am2018145
关键词
mesoporous; spheres; lithium ion batteries; glycolate; lithium titanate; high-rate
资金
- Ministry of Education
- 973 National Key Basic Research Program of China [2007CB310500]
- Chinese Ministry of Education [705040]
- National Natural Science Foundation of China [90606009]
A facile, green strategy is explored to synthesize mesoporous Au/Li4Ti5O12 spheres based on in situ conversion of titanium glycolate in LiOH aqueous solution. Compared with TiO2 precursors, titanium glycolate possesses some strengths: (i) fast and easy preparation; (ii) direct reaction with LiOH without introduce of TiO2 impurity. In the synthesis, the produced chemical waste is only the mixed solvent of acetone and ethylene glycol (EG). Furthermore, acetone and EG in chemical waste can be easily separated by distillation and reused in the next synthesis process due to the great difference between their boiling points. In particular, the as-prepared mesoporous Au/Li4Ti5O12 spheres combines the advantages of large specific surface area (166 m(2)/g) and good electronic conduction enhanced by Au nanoparticles when used as an anode electrode material. The electrochemical tests show that the mesoporous Au/Li4Ti5O12 spheres display excellent high rate capability and cycling performance.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据