期刊
ACS APPLIED MATERIALS & INTERFACES
卷 3, 期 5, 页码 1528-1537出版社
AMER CHEMICAL SOC
DOI: 10.1021/am200102y
关键词
tin sulfide; tin oxide; nanocomposites; in situ oxidation synthesis; photocatalysis; stability
资金
- China Postdoctoral Science Foundation
- Jiangsu Planned Projects for Postdoctoral Research Funds
- National Natural Science Foundation of China [50873085, 50902005]
- Natural Science Foundation of Jiangsu Province [08KJB150019]
SnS2/SnO2 nanocomposites with tunable SnO2 contents were prepared via in situ hydrothermal oxidation of SnS2 nanoparticles in 0.375-4.5 mass% H2O2 aqueous solutions at 180 degrees C for 0-12 h. The structure, composition and optical properties of the as-prepared SnS2/SnO2 nanocomposites were characterized by X-ray diffraction, transmission electron microscopy, high-resolution transmission electron microscopy, Brunauer-Emmett-Teller (BET) surface area analysis, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and UV-vis diffuse reflectance spectra. Furthermore, their photocatalytic properties were tested for the degradation of methyl orange in water under visible light (lambda > 420 nm) irradiation. It was found that the as-prepared SnS2/SnO2 nanocomposites with suitable SnO2 content not only demonstrated superior photocatalytic activity to both SnS2 nanoparticles and physically mixed SnS2/SnO2 composite nanoparticles, but also had remarkable photocatalytic stability. The tight attachment of SnO2 nanoparticles to SnS2 nanoparticles, which can facilitate interfacial electron transfer and reduce the self-agglomeration of two components, was considered to play an important role in achieving the high photocatalytic performances exhibited by the as-prepared SnS2/SnO2 nanocomposites.
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